Premier League champions Leicester City will open the 2016-17 campaign as their meeting with newly promoted Hull City has been selected for broadcast.
The fixture will be shown live on Sky Sports at the new Saturday time slot of 12:30pm on August 13, as Claudio Ranieri's men look to defend their shock championship crown.
Pep Guardiola's Manchester City bow will be broadcast by BT as part of their new live package as his side host Sam Allardyce's Sunderland at 5:30pm on the same day.
Bournemouth's opening fixture, a home clash with Manchester United, and Liverpool's trip to Arsenal will also both be shown live on Sunday, August 14.
Jose Mourinho, who was unveiled as the new United boss on Tuesday, has never lost an opening Premier League fixture.
The Portuguese will meet Guardiola on September 10, with the clash set to be shown live by Sky Sports.
The first live Monday night game will be Chelsea vs West Ham, an 8pm kick off, as Antonio Conte takes charge of the beleagured former champions for the first time.
A number of fixtures have, or will, be been rearranged as a result of Europa League participation.
See below for a full list of changes.
Fixture amendments (times are BST)
Saturday 13 August
12.30pm Hull City v Leicester City (Sky Sports)
5.30pm Manchester City v Sunderland (BT Sport)
Sunday 14 August
1.30pm Bournemouth v Manchester United (Sky Sports)
4pm Arsenal v Liverpool (Sky Sports)
Monday 15 August
8pm Chelsea v West Ham (Sky Sports)
Friday 19 August
8pm Manchester United v Southampton (Sky Sports)
Saturday 20 August
12.30pm Stoke City v Manchester City (Sky Sports)
3pm Burnley v Liverpool*
*This match was scheduled for 11 March 2017 but Liverpool and Burnley have agreed to reverse fixtures, with Liverpool v Burnley taking place on Sunday 12 March 2017 (subject to FA Cup participation or broadcast selections).
5.30pm Leicester City v Arsenal (BT Sport)
Sunday 21 August
1.30pm Sunderland v Middlesbrough (Sky Sports)
4pm West Ham v Bournemouth (Sky Sports)
Saturday 27 August
12.30pm Tottenham v Liverpool (Sky Sports)
5.30pm Hull City v Manchester United (BT Sport)
Sunday 28 August
1.30pm West Brom v Middlesbrough (Sky Sports)
4pm Manchester City v West Ham (Sky Sports)
Saturday 10 September
12.30pm Manchester United v Manchester City (Sky Sports)
5.30pm Liverpool v Leicester City (BT Sport)
Sunday 11 September
4pm Swansea City v Chelsea (Sky Sports)
Monday 12 September
8pm Sunderland v Everton (Sky Sports)
Friday 16 September
8pm Chelsea v Liverpool (Sky Sports)
Saturday 17 September
5.30pm Everton v Middlesbrough (BT Sport)
Sunday 18 September
12pm Watford v Manchester United (BT Sport)
2.15pm Crystal Palace v Stoke City (Sky Sports)
2.15pm Southampton v Swansea City*
*Southampton’s participation in the Europa League the preceding Thursday
4.30pm Tottenham Hotspur v Sunderland (Sky Sports)
Saturday 24 September
12.30pm Manchester United v Leicester City (Sky Sports)
5.30pm Arsenal v Chelsea (BT Sport)
Sunday 25 September
4pm West Ham United v Southampton (Sky Sports)
Monday 26 September
8pm Burnley v Watford (Sky Sports) - Goal